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Products from Oil

Ethanol - Properties and Formation.

Ethanol is an alcohol with the molecular formula C2H5OH
(see also the structural formula).
Ethanol is not a hydrocarbon because the molecule contains oxygen
as well as hydrogen and carbon.

Ethanol is a colourless liquid which boils at 78 °C.
It is completely miscible with water.
This means that it mixes with water in any quantity.
Ethanol is a neutral liquid.

Ethanol can be made by the fermentation of a sugar solution (batch process)
or buy the reaction of ethene with steam
in the presence of phosphoric acid (continuous process).
A continuous process means that reactants are constantly being put in
at one end of the reaction vessel and products are
constantly being taken out at the other end of the reaction vessel.

Adding the components of water
across the double bond of ethene is called the hydration of ethene.
The reaction is carried out at a high temperature and a high pressure.

ethene       +       steam         ethanol
C2H4(g)      +      H2O(l)         arrow          C2H5OH(l)

See a comparison of the batch process with the continuous process below.

Process Batch Process Continuous Process
Reaction Fermentation Hydration of Ethene
Renewable Resource? Yes - Sugar Cane No - Crude Oil
Rate of Reaction Slow Fast
Product Ethanol / Water mixture Pure Ethanol

Industry would rather use the continuous process than the batch process
because of the fast production of a pure product. In some countries
it may be more practical to use the batch process - see next page.

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